High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge     

Parham Ahmadi  Massimo Coltorti  Takeshi Kuritani  Yue Cai  Anna Maria Fioretti 《International Geology Review》2019,61(2):150-174

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.  相似文献   

A new archival infrastructure for highly-structured astronomical data     

Erik Dovgan  Cristina Knapic  Massimo Sponza  Riccardo Smareglia 《Experimental Astronomy》2018,45(1):41-55

  相似文献   

Landscape response to tectonic and climatic forcing in the foredeep of the southern Apennines,Italy: insights from Quaternary stratigraphy,quantitative geomorphic analysis,and denudation rate proxies          下载免费PDF全文

Dario Gioia  Salvatore Gallicchio  Massimo Moretti  Marcello Schiattarella 《地球表面变化过程与地形》2014,39(6):814-835

We present new data about the morphological and stratigraphic evolution and the rates of fluvial denudation of the Tavoliere di Puglia plain, a low‐relief landscape representing the northernmost sector of the Pliocene‐Pleistocene foredeep of the southern Apennines. The study area is located between the easternmost part of the southern Apennine chain and the Gargano promontory and it is characterized by several orders of terraced fluvial deposits, disconformably overlying lower Pleistocene marine clay and organized in a staircase geometry, which recorded the emersion and the long‐term incision history of this sector since mid‐Pleistocene times. We used the spatial and altimetric distribution of several orders of middle to late Pleistocene fluvial terraces in order to perform paleotopographic reconstruction and GIS‐aided eroded volumes estimates. Then, we estimated denudation rates on the basis of the terraces chronostratigraphy, supported by published OSL and AAR dating. Middle to upper Pleistocene denudation rates estimated by means of such an approach are slightly lower than 0.1 mm yr^‐1, in good agreement with short‐term data from direct and indirect evaluation of suspended sediment yield. The analysis of longitudinal river profiles using the stream power erosion model provided additional information on the incision rates of the studied area. Middle to late Quaternary uplift rates (about 0.15 mm yr^‐1), calculated on the basis of the elevation above sea level of marine deposits outcropping in the easternmost sector of the study area, are quite similar to the erosion rates average value, thus suggesting a steady‐state fluvial incision. The approach adopted in this work has demonstrated that erosion rates traditionally obtained by quantitative geomorphic analysis and k_sn estimations can be successfully integrated to quantify rates of tectonic or geomorphological processes of a landscape approaching steady‐state equilibrium. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

U?Pb and 40Ar?39Ar geochronology of Palaeozoic units in the northern Apennines: determining protolith age and alpine evolution using the Calamita Schist and Ortano Porphyroid     

Giovanni Musumeci  Francesco Mazzarini  Massimo Tiepolo  Gianfranco Di Vincenzo 《Geological Journal》2011,46(4):288-310

In the northern Apennines, the Palaeozoic basement involved in the Late Oligocene–Middle Miocene nappe stack contains metamorphic units for which hypothetical ages have been assigned on the basis of lithological correlations with the Palaeozoic formations of the Variscan chain in Sardinia. This uncertainty concerning the age poses limitations to reconstructing the Palaeozoic stratigraphy, defining the Alpine and pre‐Alpine histories and correlations with other domains of the Variscan chain. We present the U Pb age of detrital zircon and the ⁴⁰Ar ³⁹Ar age of metamorphic muscovite for the Calamita Schist and Ortano Porphyroid, two metamorphic units of undetermined Palaeozoic age cropping out in the eastern Elba Island. The radioisotopic data allows us to: (i) define the Early Carboniferous and Middle Ordovician ages for the Calamita Schist and Ortano Porphyroid, respectively, as well as their derivation (flysch deposit and magmatic rocks); (ii) pose some constraints concerning their alpine tectonic and metamorphic histories. These new data generate a more precise reconstruction of the Palaeozoic sequence in the northern Apennines, and they document that the Palaeozoic basement involved in the alpine deformation underwent internal stacking with an inversion of the original sequence. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Sensitivity analysis of CDOM spectral slope in artificial and natural samples: an application in the central eastern Mediterranean Basin     

Luca Bracchini  Antonio Tognazzi  Arduino Massimo Dattilo  Franco Decembrini  Claudio Rossi  Steven Arthur Loiselle 《Aquatic Sciences - Research Across Boundaries》2010,72(4):485-498

In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution. We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating that consistent values may be determined, with a typical uncertainty of ±0.0004 nm⁻¹ when absorption at 300 nm was greater then 0.1 m⁻¹ (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution, we show differences between measurements that were significantly different. These values allow us to distinguish possible sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or near deep chlorophyll maximum.  相似文献   

New insights on the origin of troctolites from the breakaway area of the Godzilla Megamullion (Parece Vela back‐arc basin): The role of melt‐mantle interaction on the composition of the lower crust          下载免费PDF全文

Alessio Sanfilippo  Henry J. B. Dick  Yasuhiko Ohara  Massimo Tiepolo 《Island Arc》2016,25(3):220-234

The troctolites and olivine‐gabbros from the Dive 6 K‐1147 represent the most primitive gabbroic rocks collected at the Godzilla Megamullion, a giant oceanic core complex formed at an extinct spreading segment of the Parece Vela back‐arc basin (Philippine Sea). Previous investigations have shown that these rocks have textural and major elements mineral compositions consistent with a formation through multistage interaction between mantle‐derived melts and a pre‐existing ultramafic matrix. New investigations on trace element mineral compositions basically agree with this hypothesis. Clinopyroxenes and plagioclase have incompatible element signatures similar to that of typical‐MORB. However, the clinopyroxenes show very high Cr contents (similar to those of mantle clinopyroxene) and rim having sharply higher Zr/REE ratios with respect to the core. These features are in contrast with an evolution constrained by fractional crystallization processes, and suggest that the clinopyroxene compositions are controlled by melt‐rock interaction processes. The plagioclase anorthite versus clinopyroxene Mg#[Mg/(Mg + Fe^Tot)] correlation of the Dive 6 K‐1147 rocks shows a trend much steeper than those depicted by other oceanic gabbroic sections. Using a thermodynamic model, we show that this trend is reproducible by fractionation of melts assimilating 1 g of mantle peridotite per 1 °C of cooling. This model predicts the early crystallization of high Mg# clinopyroxene, consistent with our petrological observation. The melt‐peridotite interaction process produces Na‐rich melts causing the crystallization of plagioclase with low anorthite component, typically characterizing the evolved gabbros from Godzilla Megamullion.  相似文献   

Compositionally zoned crystals and real-time degassing data reveal changes in magma transfer dynamics during the 2006 summit eruptive episodes of Mt. Etna     

Maren Kahl  Sumit Chakraborty  Fidel Costa  Massimo Pompilio  Marco Liuzzo  Marco Viccaro 《Bulletin of Volcanology》2013,75(2):1-14

One of the major objectives of volcanology remains relating variations in surface monitoring signals to the magmatic processes at depth that cause these variations. We present a method that enables compositional and temporal information stored in zoning of minerals (olivine in this case) to be linked to observations of real-time degassing data. The integrated record may reveal details of the dynamics of gradual evolution of a plumbing system during eruption. We illustrate our approach using the 2006 summit eruptive episodes of Mt. Etna. We find that the history tracked by olivine crystals, and hence, most likely the magma pathways within the shallow plumbing system of Mt. Etna, differed considerably between the July and October eruptions. The compositional and temporal record preserved in the olivine zoning patterns reveal two mafic recharge events within months of each other (June and September 2006), and each of these magma supplies may have triggered the initiation of different eruptive cycles (July 14–24 and August 31–December 14). Correlation of these observations with gas monitoring data shows that the systematic rise of the CO₂/SO₂ gas values is associated with the gradual (pre- and syn-eruptive) supply of batches of gas-rich mafic magma into segments of Etna’s shallow plumbing system, where mixing with pre-existing and more evolved magma occurred.  相似文献   

Volcanic ash detection by GPS signal     

Massimo Aranzulla  Flavio Cannavò  Simona Scollo  Giuseppe Puglisi  Giuseppina Immè 《GPS Solutions》2013,17(4):485-497

We investigate the ability of GPS to detect volcanic plumes at Mt. Etna, Italy. We use a robust statistical approach to highlight whether the presence of a volcanic plume in the atmosphere may really affect the GPS undifferenced post-fit phase residuals. The proposed method has been tested for the September 4–5, 2007 activity of Mt. Etna. This eruption produced powerful lava fountains forming a weak, a few kilometers high plume for several hours, representing typical activity at Etna over the last 5 years. We analyzed data from nineteen Etna permanent GPS stations located on the volcano flanks at different heights and applied a statistical test based on four main steps: (a) realization of a simplified model representing the volcanic plume in atmosphere; (b) evaluation of the GPS satellite and station couples intersecting the plume; (c) calculation of the volcanic plume region crossed by the GPS signal; (d) application of a robust statistical test in order to see whether the volcanic plume affected the GPS signals. Results show that during the September 4–5, 2007 explosive activity, the GPS residuals definitely include the contribution of the volcanic plume. Our analysis shows that values of the GPS residuals are ten times smaller than those found for the Miyakejima eruption (Japan), highlighting a likely relationship between residuals and eruption intensity. In the future, data derived from the GPS stations located on Etna’s flanks could be used to improve the alerting system of volcanic ash, already operating at the Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Etneo.  相似文献   

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects     

Maurizio?Romanelli  Francesco?Di BenedettoEmail author  Laura?Bartali  Massimo?Innocenti  Gabriele?Fornaciai  Giordano?Montegrossi  Luca?A.?Pardi  Alfonso?Zoleo  Fabio?Capacci 《Physics and Chemistry of Minerals》2012,39(6):479-490

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.  相似文献   

Geochemistry and zircon U-Pb geochronology of Aligoodarz granitoid complex, Sanandaj-Sirjan Zone, Iran     

Amir Esna-Ashari  Massimo TiepoloMohammad-Vali Valizadeh  Jamshid HassanzadehAli-Asghar Sepahi 《Journal of Asian Earth Sciences》2012,43(1):11-22

The Aligoodarz granitoid complex (AGC) is located in the Sanandaj-Sirjan Zone (SSZ), western Iran and consists of quartz-diorites, granodiorites and subordinate granites. Whole rock major and trace element data mostly define linear trends on Harker diagrams suggesting a cogenetic origin of the different rock types. (⁸⁷Sr/⁸⁶Sr)_i and εNd_t ratios are in the ranges 0.7074-0.7110 and −3.56 to −5.50, respectively. The trace elements and Sr-Nd isotopic composition suggest that the granitoids from the AGC are similar to crustal derived I-type granitoids of continental arcs. The whole rock suite was produced by assimilation and fractional crystallization starting from a melt with intermediate composition likely possessing a mantle component. In situ zircon U-Pb data on the granites with LA-ICP-MS yield a crystallization age of ∼165 Ma. Inherited grains spanning in age from ∼180 Ma up to 2027 Ma were also found and confirm that assimilation of country rock has occurred.Chemical and chronological data on the AGC were compared with those available for other granitoid complexes of the central SSZ (e.g., Dehno, Boroujerd and Alvand). The comparison reveals that in spite of the different origins that have been proposed, all these granitoid complexes are likely genetically related. They share many chemical features and are derived from crustal melts with minor differences. Alvand granites have the most peculiar compositions most likely related to the presence of abundant pelitic component. All these intrusions are coeval and reveal the presence of an extensive magmatic activity in the central sector of the SSZ during middle Jurassic.  相似文献